The Radiation Chemistry of Macromolecules. Volume II by Malcolm Dole

By Malcolm Dole

The Radiation Chemistry of Macromolecules, quantity II is a set of papers that discusses radiation chemistry of particular platforms. half 1 bargains with radiation chemistry of substituted vinyl polymers, really polypropylene (PP) as its constitution is intermediate among polyethylene and polyisobutylene. This half additionally discusses polypropylene oxide (PPOx) for it may be ready within the atactic, isotactic, and optically energetic types. One paper makes a speciality of the elemental chemical tactics and the alterations in actual homes that provide upward thrust to many various purposes of polystyrene. one other paper analyzes poly(methyl methacrylate) and poly(isobutylene)—two very important polymers of nongelling elements topic to radiation. half 2 describes the radiation chemistry of a few miscellaneous polymers together with the formation of loose radicals and their termination. One paper additionally considers the radiation chemistry of polytetrafluoroethyle (PTFE), that is conventional in undefined. half three discusses the influence of radiation on oxidation, mechanical homes, and actual nation of polymers. half four addresses macromolecules, really the radiation chemistry of biopolymers as a result of their position in radiation chemistry. the wear and tear performed to biopolymers via radiation can impact the responses of residing organisms to ionizing radiation. This publication can turn out worthwhile to scientists and researchers within the fields of nuclear biology, nuclear technology, microchemistry, and mobile biology.

Show description

By Malcolm Dole

The Radiation Chemistry of Macromolecules, quantity II is a set of papers that discusses radiation chemistry of particular platforms. half 1 bargains with radiation chemistry of substituted vinyl polymers, really polypropylene (PP) as its constitution is intermediate among polyethylene and polyisobutylene. This half additionally discusses polypropylene oxide (PPOx) for it may be ready within the atactic, isotactic, and optically energetic types. One paper makes a speciality of the elemental chemical tactics and the alterations in actual homes that provide upward thrust to many various purposes of polystyrene. one other paper analyzes poly(methyl methacrylate) and poly(isobutylene)—two very important polymers of nongelling elements topic to radiation. half 2 describes the radiation chemistry of a few miscellaneous polymers together with the formation of loose radicals and their termination. One paper additionally considers the radiation chemistry of polytetrafluoroethyle (PTFE), that is conventional in undefined. half three discusses the influence of radiation on oxidation, mechanical homes, and actual nation of polymers. half four addresses macromolecules, really the radiation chemistry of biopolymers as a result of their position in radiation chemistry. the wear and tear performed to biopolymers via radiation can impact the responses of residing organisms to ionizing radiation. This publication can turn out worthwhile to scientists and researchers within the fields of nuclear biology, nuclear technology, microchemistry, and mobile biology.

Show description

Read Online or Download The Radiation Chemistry of Macromolecules. Volume II PDF

Best chemistry books

Supramolecular Chemistry

The 1st NATO technological know-how discussion board used to be held in Biarritz in September 1990. This Taormina convention is the second one in a sequence that we want to be a protracted one and that i think that it has equalled the luck of its predecessor. In developing those conferences the NATO technological know-how Committee desired to assemble major specialists to check fields of robust current curiosity.

Additional resources for The Radiation Chemistry of Macromolecules. Volume II

Sample text

Loy, B. R. (1961). /. Polym. Sei. 50, 245. McNeill, I. C , and Neil, D. (1970). Eur. Polym. J. 6, 143. Miller, A. A. (1959). /. Phys. Chem. 63, 1755. Ouchi, I. (1965). /. Polym. Sei. A 3, 2685. Posselt, K. (1968). Kolloid-Z. Z. Polym. 223, 104. Rao, C. N. R. (1967). , p. 53. Plenum Press, New York. , and Bair, H. E. (1970). /. Appl. Polym. Sei. 14, 713. , and Luongo, J. P. (1970). J. Polym. A-1 8, 209. , Luongo, J. , and Yager, W. A. (1969). Macromolecules 2, 198. , Albarino, R. , and Luongo, J.

1970). J. Polym. A-1 8, 209. , Luongo, J. , and Yager, W. A. (1969). Macromolecules 2, 198. , Albarino, R. , and Luongo, J. P. (1970). Macromolecules 3, 314. , Ben-Efraim, D. , and Wolovsky, R. (1961). /. Amer. Chem. Soc. 83, 1675. Suzuki, H. (1967). "Electronic Absorption Spectra and Geometry of Organic Molecules," p. 361. Academic Press, New York. Waterman, D. C , and Dole, M. (1970). J. Phys. Chem. 74, 1906. 41 Polyvinyl Acetate William W. Graessley Chemical Engineering Department, Northwestern University, Evans ton, Illinois I.

Aulov et al. (1968) irradiated PP at liquid helium temperature and observed thermoluminescence peaks at —90° to - 7 0 ° and -150° to -140°. Mozisek (1967) also found a pronounced thermoluminescence peak at — 150°. Thermoluminescence is believed to be associated with the untrapping of 24 D. O. Geymer electrons as molecular motions become possible. The peak at —150° appears at the same temperature at which the ESR spectrum of the radicals dominant at room temperature changes from 17 lines to 9, a change which was attributed to hindered oscillations of methyl and/or méthylène groups.

Download PDF sample

Rated 4.24 of 5 – based on 31 votes