The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, by Stanley E. Livingstone (Auth.)

By Stanley E. Livingstone (Auth.)

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By Stanley E. Livingstone (Auth.)

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Ibid. Ibid. Ibid. J. P. Collman and W. R. Roper, Chem. Communs. 1966, 244. E. O. Fischer and J. Müller, Ber. 96 (1963) 3217. S. D. Robinson and G. Wilkinson, / . Chem. Soc. A, 1966, 300. Ibid. M. I. Bruce and F. G. A. Stone, Angew. , Int. , 7 (1968) 427. Ibid. A number of diene complexes are known: [QH^RuCOCbk (C8Hi2 = cyclo-octa1,5-diene), [C8H12RuX2],, (X = Cl, Br, I), CsHnRuChp-NHîCeï^Me, [C7H8RuCl2]n (C7H8 = norbornadiene), C7H8RuCl2/>-NH2C6H4Me and C7H8Ru(PPh3)2X2 (X = Cl, Br) 121. 121 M. A.

4,4'-Dichlorophenylacetylene gives [(ClC6H4)2C2]3Ru3(CO)9 and Ph wc SLU(CO) 3 (ii) 77 F. Piacenti, P. Pino, M. Bianchi, G. Braca and G. Sbrana, Progress in Coordination Chemistry (M. ), Elsevier, Amsterdam (1968), p. 54. 78 M. I. Bruce, M. Cooke and M. Green, / . Organomet. Chem. 13 (1968) 227. ™ T. Kruck, Angew. Chem. 6 (1967) 53. so J. Müller and E. O. Fischer, / . Organomet. Chem. 5 (1966) 277. 81 D. Jones, L. Pratt and G. Wilkinson, / . Chem. Soc. 1962, 4458. 1198 GROUP VIII A, B AND C: STANLEY E.

X-ray fluorescence spectroscopy has been used for the determination of rhodium, iridium, palladium and platinum45. 40 F. E. Beamish and W. E. A. McBryde, Anal. Chim. Acta 9 (1953) 349; 18 (1958) 551. 41 A. Walsh and J. B. Willis, Atomic Absorption Spectrometry, chap. , Vol. 3A (F. J. J (1966), p. 105. 42 W. T. Elwell and J. A. F. , International Series of Monographs on Analytical Chemistry, Vol. 6, Pergamon, New York (1966). « R. Lockyer and G. E. Hames, Analyst, 84 (1959) 385. 44 V. L. Ginzburg, D.

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