The Chemistry of Organolithium Compounds (PATAI'S Chemistry by Zvi Z. Rappoport, Ilan Marek

By Zvi Z. Rappoport, Ilan Marek

This can be the 1st quantity within the sequence to pay attention to organo-lithium compounds - the sub sequence "The chemistry of the metal-carbon bond" (5 vol) handled organometallics in general.It offers with theoretical/physical/computational apsects, in addition to significant spectroscopies, akin to MS, NMR, IR/UV and so forth and either organic and commercial applications.The middle of the amount is the substitute chapters with plenty of examples for contemporary artificial approachesWritten by way of key researchers within the fieldAn necessary reference resource to natural chemists operating in academia and industryFeatures very important reagents in natural synthesis

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By Zvi Z. Rappoport, Ilan Marek

This can be the 1st quantity within the sequence to pay attention to organo-lithium compounds - the sub sequence "The chemistry of the metal-carbon bond" (5 vol) handled organometallics in general.It offers with theoretical/physical/computational apsects, in addition to significant spectroscopies, akin to MS, NMR, IR/UV and so forth and either organic and commercial applications.The middle of the amount is the substitute chapters with plenty of examples for contemporary artificial approachesWritten by way of key researchers within the fieldAn necessary reference resource to natural chemists operating in academia and industryFeatures very important reagents in natural synthesis

Show description

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Extra resources for The Chemistry of Organolithium Compounds (PATAI'S Chemistry of Functional Groups)

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B. C5 Perimeter . . . . . . . . . . . . . . . . . . . 1. Polymeric lithium cyclopentadienyl derivatives . . . . . . . 2. Molecular fractions of polymeric lithium cyclopentadienyl derivatives . . . . . . . . . . . . . . . . . . . 3. Monomeric lithium cyclopentadienyl derivatives . . . . . . 4. Lithium indenyl derivatives . . . . . . . . . . . . . 5. Dilithium organics with fused C5 and C6 perimeters . . . . . 6. Lithium fluorenyl derivatives .

MNDO-determined structures of intermediates and transition states for the cleavage of cinnamyl and phenylpropenyl ethers 18 and 19, through anion-radical routes involving contact ion pairs (CIP) and isolated ion pairs (IIP). All energies are in kcal mol−1 . Geometrical features relevant to haptomeric activation are shown: (1) C−OMe bond length and bond order (in brackets), (2) Li−OMe distance and (3) enthalpy of formation. Reprinted with permission from Reference 22. Copyright 1996 American Chemical Society 1.

B. C5 Perimeter . . . . . . . . . . . . . . . . . . . 1. Polymeric lithium cyclopentadienyl derivatives . . . . . . . 2. Molecular fractions of polymeric lithium cyclopentadienyl derivatives . . . . . . . . . . . . . . . . . . . 3. Monomeric lithium cyclopentadienyl derivatives . . . . . . 4. Lithium indenyl derivatives . . . . . . . . . . . . . 5. Dilithium organics with fused C5 and C6 perimeters . . . . . 6. Lithium fluorenyl derivatives .

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