Preparation, Characterisation and Reactivity of Low by Jamie Hicks

By Jamie Hicks

This thesis describes the synthesis and characterization of diverse metal-metal bonded complexes which are stabilized by way of super cumbersome amide ligands. It presents a entire evaluate of the sector, together with discussions on groundbreaking complexes and reactions, sooner than featuring intimately, intriguing new findings from the PhD reviews. The thesis appeals to researchers, professors and chemistry undergraduates with an curiosity in inorganic and/or organometallic chemistry.

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By Jamie Hicks

This thesis describes the synthesis and characterization of diverse metal-metal bonded complexes which are stabilized by way of super cumbersome amide ligands. It presents a entire evaluate of the sector, together with discussions on groundbreaking complexes and reactions, sooner than featuring intimately, intriguing new findings from the PhD reviews. The thesis appeals to researchers, professors and chemistry undergraduates with an curiosity in inorganic and/or organometallic chemistry.

Show description

Read Online or Download Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands PDF

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Additional resources for Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands

Sample text

The structures of 2-02 and 2-03 were determined by X-ray crystallography, and were found to be essentially isostructual to the previously reported amido iron(II) chloride 2-01. 87 µB for high spin Co2+ with Td geometry). Complexes 2-02 and 2-03 were further reacted with methyl lithium, resulting in moderate yields of the corresponding methylated complexes [Fe(Me){N (SiMe3)(Xyl)}(tmeda)] 2-04 and [Co(Me){N(SiMe3)(Xyl)}(tmeda)] 2-05 [6]. However, once again, no attempts were made to reduce the complexes, in order to isolate a low oxidation state amido iron or cobalt complex.

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