Physico-Chemical Phenomena in Thin Films and at Solid by Leonid I. Trakhtenberg, Sheng H. Lin, Olusegun J. Ilegbusi

By Leonid I. Trakhtenberg, Sheng H. Lin, Olusegun J. Ilegbusi

The publication is dedicated to the distinction of the several tactics occurring in skinny movies and at surfaces. because the most vital physico-chemical phenomena in such media are followed through the rearrangement of an intra- and intermolecular coordinates and as a result a surrounding molecular ensemble, the speculation of radiationless multi-vibrational transitions is used for its description. the second one a part of the ebook considers the various floor phenomena. And within the 3rd half is defined the training equipment and features of other forms of skinny movies. either experimental and theoretical descriptions are represented. Media rearrangement coupled with the reagent transformation mostly determines absolutely the worth and temperature dependence of the speed constants and different features of the thought of tactics. those results are defined on the atomic or molecular point in response to the multi-phonon thought, ranging from the 1st pioneering reports via to modern reviews. a couple of questions are integrated on the finish of many chapters to extra strengthen the fabric offered. · Unified method of the outline of various physico-chemical phenomena in numerous fabrics · in response to the pioneering examine paintings of the authors · Explantion of quite a few experimental observations · fabric is gifted at degrees of complexity for experts and non-specialists · Identifies latest and strength purposes of the tactics and phenomena · comprises questions on the finish of a few chapters to additional make stronger the fabric mentioned

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By Leonid I. Trakhtenberg, Sheng H. Lin, Olusegun J. Ilegbusi

The publication is dedicated to the distinction of the several tactics occurring in skinny movies and at surfaces. because the most vital physico-chemical phenomena in such media are followed through the rearrangement of an intra- and intermolecular coordinates and as a result a surrounding molecular ensemble, the speculation of radiationless multi-vibrational transitions is used for its description. the second one a part of the ebook considers the various floor phenomena. And within the 3rd half is defined the training equipment and features of other forms of skinny movies. either experimental and theoretical descriptions are represented. Media rearrangement coupled with the reagent transformation mostly determines absolutely the worth and temperature dependence of the speed constants and different features of the thought of tactics. those results are defined on the atomic or molecular point in response to the multi-phonon thought, ranging from the 1st pioneering reports via to modern reviews. a couple of questions are integrated on the finish of many chapters to extra strengthen the fabric offered. · Unified method of the outline of various physico-chemical phenomena in numerous fabrics · in response to the pioneering examine paintings of the authors · Explantion of quite a few experimental observations · fabric is gifted at degrees of complexity for experts and non-specialists · Identifies latest and strength purposes of the tactics and phenomena · comprises questions on the finish of a few chapters to additional make stronger the fabric mentioned

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A. Krivoglaz, J. Exp. Theor. Phys. 25 (1953) 191. K. Husimi, Proc. Phys. Math. Soc. Japan 22 (1940) 406. V. G. Levich, R. R. Dogonadze, Dokl. Phys. Chem. 124 (1959) 123; V. G. Levich, R. R. Dogonadze, Dokl. Phys. Chem. 133 (1960) 158. R. R. Dogonadze, Dokl. Phys. Chem. 133 (1960) 258. R. R. Dogonadze, Yu. A. Chizmadzhev, Dokl. Phys. Chem. 144 (1962) 1077. R. R. Dogonaze, A. M. Kuznetsov, Yu. A. Chizmadzhev, Russ. J. Phys. Chem. 38 (1964) 1195. R. R. Dogonaze, A. M. Kuznetsov, Electrochemistry 3 (1967) 1324.

Chem. 124 (1959) 123; V. G. Levich, R. R. Dogonadze, Dokl. Phys. Chem. 133 (1960) 158. R. R. Dogonadze, Dokl. Phys. Chem. 133 (1960) 258. R. R. Dogonadze, Yu. A. Chizmadzhev, Dokl. Phys. Chem. 144 (1962) 1077. R. R. Dogonaze, A. M. Kuznetsov, Yu. A. Chizmadzhev, Russ. J. Phys. Chem. 38 (1964) 1195. R. R. Dogonaze, A. M. Kuznetsov, Electrochemistry 3 (1967) 1324. CONVENTIONAL THEORY OF MULTI-PHONON ELECTRON TRANSITIONS 35 24. A. A. Ovchinnikov, M. Ya. Ovchinnikova, J. Exp. Theor. Phys. 56 (1969) 1278.

But as it will be shown in the following sections, the medium’s influence on Vif is much stronger where the crystal and electron structures of the medium play a role. Besides, it was supposed in deducing the expression for Vif that the electron bound energies E on the donor and acceptor are equal, or in other words, the energy transmitted to the vibrations, DEooE, changes the function exp{ÀkrDA} very weakly at the replacement of E in E7DE. The influence of the energy defect DE on the matrix element Vif and the connection of the electron and nuclei degrees of freedom at electron transfer will be examined in Section 5 of this chapter.

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