By J. E. Enderby (auth.), Gleb Mamantov, Roberto Marassi (eds.)
Molten salts are of substantial importance to chemical expertise. purposes diversity from the verified ones, comparable to the construction of aluminum, magnesium, sodium and fluorine, to these as but to be absolutely exploited, equivalent to molten salt batteries and gasoline cells, catalysis, and solar power. Molten salts are investigated for various reasons by means of many assorted suggestions. there's a have to continue investigators operating in several components, corresponding to steel construction, strength assets, and glass undefined, conscious of growth in a number of specialties, in addition to to familiarize new learn employees with the elemental features of the huge box of molten salt _ chemistry. This quantity constitutes the plenary lectures provided on the NATO complicated research Institute on Molten Salt Chemistry, Camerino, Italy, August 3-15, 1986. the basics and a number of other chosen purposes of molten salt chemistry have been addressed. the most important primary subject matters coated at this ASI have been the constitution of melts, thermodynamics of molten salt combos, theoretical and experimental experiences of shipping methods, metal-metal salt recommendations, solvent houses of soften structures, acid-base results in molten salt chemistry, digital absorption, vibrational, and nuclear magnetic resonance spectroscopy of soften platforms, electrochemistry and electroanalytical chemistry in molten salts, and natural chemistry in molten salts. The utilized facets of molten salt chemistry integrated the chemistry of aluminum construction, electrodeposition utilizing molten salts, and molten salt batteries and gasoline cells.
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Extra info for Molten Salt Chemistry: An Introduction and Selected Applications
3 I - - - - - - ; - - - - - + - - - - - . 2 >-. 1 o Fig. 2 o 2 logarithms of the activ~ty coefficie~ts of AgI~03 molten NaN0 3 as a funct~on of the an~on fractHin of chloride at seven temperatures. The limiting slopes of the curves at low chloride concentrations is proportional to the negative of the formation constant for the Agel species in solution. BLANDER . ) Z 4 Z = 5 Z 6 623 643 658 675 696 709 a. 62 553 408 460 396 348 315 604 637 658 675 696 711 773 b. 55 277 226 205 176 160 146 110 506 551 658 752 801 c.
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