Inorganic Chemistry of the Transition Elements: v. 3: A by Brian Frederick Gilbert Johnson

By Brian Frederick Gilbert Johnson

Expert Periodical studies supply systematic and designated overview assurance of development within the significant parts of chemical study. Written by means of specialists of their expert fields the sequence creates a different carrier for the lively study chemist, delivering commonplace severe in-depth debts of development particularly parts of chemistry.

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By Brian Frederick Gilbert Johnson

Expert Periodical studies supply systematic and designated overview assurance of development within the significant parts of chemical study. Written by means of specialists of their expert fields the sequence creates a different carrier for the lively study chemist, delivering commonplace severe in-depth debts of development particularly parts of chemistry.

Show description

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Lo' M. Sinibaldi, J . , 1973,76,280. l o 6 D. Schwarzenbach, Hell). Chim. Acta, 1972. 55, 2990. lo' G. Perrault, C. Boucher, J. Vicat, E. Cannillo. and G. , 1973. B29, 1432. l o 8 L. Dauerman and G . E. Salser, J . Inorg. , 1973, 35, 304. '~~ A new and cubic phase of KTi,(POJ, has been prepared which is isotypic with langbeinite. "' The system Ti0,-Cr,O,-SO,-H,O in 80% H,SO, has been studied at its boiling point and shown to form a range of double salts (Ti0,),(Cr02),S0, (n = 0 . 1 4 . r. ' l4 Light-scattering data have been obtained'15 which support the formation of Ti(S0J2,MS0, (M = Ca or Ba) double salts from their constituents dissolved in 98 % H'SO,.

K. Mel'nikov, V. V. Ilyukhin, A. A. Voronkov, and N. V. Belov, lzvest. Akad. R.. neorg. Materialy, 1973, 9, 530. (1) G. M. H. Van de Velde, U. Spitsbergen, and P. J. Gellings, J. lnorg. Nuclear Chew.. 1973, 35, 675. (k) B. M. Wanklyn, J . , 1972, 7, 813. (0 A. I. Sheinkman, L. M. Gol'dshtein, V. N. Turlakov, and G. V. Kleshchev, Zhur. , 1972, 45, 940. (m) M. L. Barsukova, V. A. Kuznetsov, A. N. Lobachev, and T. N. (n) C . G. Macarovici and G. Morar, Z . anorg. , 1972, 393,275. (0)B. I. Danil'tsev, T.

R. 147 N-Donor Ligands. (Me,Si),N reacts with TiCl, to yield the novel heterocyclic [Cl,TiNSiMe,],, isolated as orange c r y ~ t a 1 s . ' 5 0 TiX4,n(3-cyanopyridine)(X = C1 or Br and n = 1 or 2) complexes have been prepared from their constituent molecules by mixing in a chlorinated hydrocarbon solvent. r. ' 5 1 The complexes TiCl,L, have been characterized, where L is a unidentate, aromatic Schiff base derived from benzaldehyde, anisaldehyde, or salicylaldehyde and amines such as aniline, o-, m-,or p-toluidine or other substituted anilines.

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