The Gallery of English Costume. Picture book number eight, by coll.

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12c), most particles were segregated along the interfaces between PS and P2VP, while for the lowest density (Fig. 12d) all the nanoparticles were at the interfaces. 3 chains/nm2 did not fully shield the Au nanoparticle surface for interacting with the P2VP block. There was a favorable interaction between gold and P2VP while PS/gold interaction was weaker [62]. They demonstrated such a favorable interaction by secondary ion mass spectrometry (DSIMS). They also prepared nanocomposites with P2VP-Au nanoparticles and PS-b-P2VP block copolymer.

Mater. , 21, pp. 9271–9278. 69. , Liu, Y. , Xie, X. , Ye, X. , Chen, Y. , and Wang, Y. H. (2012). High-concentration aliphatic and aromatic dispersions of single- and few-layer graphene noncovalently modified by block copolymer crystallization, Carbon, 50, pp. 4760–4764. 70. , Liu, J. , Barrow, C. , and Yang, W. R. (2013). Preparation of graphene/polymer composites by direct exfoliation of graphite in functionalised block copolymer matrix, Carbon, 51, pp. 148–155. 71. , Yan, H. , Wang, C. , and Tagmatarchis, N.

S. Douadi-Masrouki et al. [47] also grafted PS brushes from magnetic g-Fe2O3 nanoparticles surface by ATRP in order to incorporate them into lamellar poly(styrene-b-butyl methacrylate) (PS-b-PBMA) diblock copolymer films. Nanoparticles were synthesized in aqueous medium, stabilized with oleate. Then an ATRP initiator (2-bromo-2-methylpropionic, BrMPA) was coated onto nanoparticles via ligand-exchange reaction [51]. They used CuBr as catalyst. They obtained brushes with molecular weights Nanocomposites Based on Block Copolymers and Polymer-Grafted Nanoparticles ranging from 15500 to 45800 g/mol.

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